Which of these pairs of archenemies have the most sparks fly while sharing the screen? Note: mild spoilers. Also note: some of the pairs have survived numerous incarnations on TV and of those the more recent ones were mostly chosen.
Andrew Scott and Benedict Cumberbatch in Sherlock (2010)
"Sherlock": Sherlock Holmes and Jim Moriarty.
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#2
"MacGyver": MacGyver and Murdoc.
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John Barrowman and Stephen Amell in Arrow (2012)
"Arrow": Oliver Queen and Malcolm Merlyn.
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Matt Letscher and Grant Gustin in The Flash (2014)
"The Flash": The Flash and Reverse-Flash.
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Michael Rosenbaum and Tom Welling in Smallville (2001)
"Smallville": Clark Kent and Lex Luthor.
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Michael C. Hall and Erik King in Dexter (2006)
"Dexter": Dexter Morgan and James Doakes.
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Peter Capaldi, Michelle Gomez, and John Simm in Doctor Who (2005)
"Doctor Who": The Doctor and The Master.
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Cameron Monaghan and David Mazouz in Gotham (2014)
"Gotham": Bruce Wayne and Jerome Valeska.
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David Tennant and Krysten Ritter in Jessica Jones (2015)
"Jessica Jones": Jessica Jones and Kilgrave.
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Neal McDonough, Courtney Ford, and Caity Lotz in DC's Legends of Tomorrow (2016)
"DC's Legends of Tomorrow": Sara Lance and Damien Darhk.
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Giancarlo Esposito and Bryan Cranston in Breaking Bad (2008)
"Breaking Bad": Walter White and Gustavo "Gus" Fring.
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Erik LaRay Harvey and Mike Colter in Luke Cage (2016)
"Luke Cage": Luke Cage and Willis "Diamondback" Stryker.
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Rose McIver and David Anders in iZombie (2015)
"iZombie": Olivia Moore and Blainde DeBeers.
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David Duchovny and William B. Davis in The X-Files (1993)
"X-Files": Fox Mulder and Smoking Man.
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Arthur Darvill and Casper Crump in DC's Legends of Tomorrow (2016)
"DC's Legends of Tomorrow": Rip Hunter and Vandal Savage.
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Rowan Atkinson in Mr. Bean: The Animated Series (2002)
"Mr. Bean": Mr. Bean and an unseen driver of Reliant Regal car.
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Jon Bernthal, Ben Barnes, and Deantre Williams in The Punisher (2017)
"The Punisher": Frank "The Punisher" Castle and Billy Russo.
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Ben McKenzie and Robin Lord Taylor in Pilot (2014)
"Gotham": James Gordon and Oswald "Penguin" Cobblepot.
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Kyle MacLachlan and Kenneth Welsh in Twin Peaks (1990)
"Twin Peaks": Dale Cooper and Windom Earle.
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Kyle MacLachlan in Twin Peaks (2017)
"Twin Peaks": Dale Cooper and his doppelganger.
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Michael Dorn, Stephen Amell, and Josh Segarra in Arrow (2012)
"Arrow": Arrow and Prometheus.
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Richard Kiel and Michael Dunn in The Wild Wild West (1965)
"The Wild Wild West": James T. West and Dr. Miguelito Loveless.
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Alyssa Milano, James Read, and Julian McMahon in Charmed (1998)
"Charmed": Phoebe Halliwell and Cole Turner.
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John Lithgow and Michael C. Hall in Dexter (2006)
"Dexter": Dexter Morgan and Arthur "The Trinity Killer" Mitchell.
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Christian Camargo and Michael C. Hall in Dexter (2006)
"Dexter": Dexter Morgan and Rudy Cooper.
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Clark Gregg and Brett Dalton in Agents of S.H.I.E.L.D. (2013)
"Agents of S.H.I.E.L.D": Phil Coulson and Grant Ward.
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Vincent D'Onofrio and Charlie Cox in Daredevil (2015)
"Daredevil": Matt "Daredevil" Murdock and Wilson "Kingpin" Fisk.
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Zachary Quinto and Milo Ventimiglia in Heroes (2006)
"Heroes": Peter Petrelli and Sylar.
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Madeleine Stowe and Emily VanCamp in Revenge (2011)
"Revenge": Victoria Grayson and Emily Thorne.
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Alexander Skarsgård and Denis O'Hare in True Blood (2008)
"True Blood": Eric Northman and Russell Edgington.
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Paul Wesley and Nina Dobrev in The Vampire Diaries (2009)
"The Vampire Diaries": Stefan Salvatore and Katherine Pierce.
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Christopher Lambert and Chris O'Donnell in NCIS: Los Angeles (2009)
"NCIS: Los Angeles": J. Callen and Marcel "Chameleon" Janvier.
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Jeff Daniels and Jack O'Connell in Godless (2017)
"Godless": Frank Griffin and Roy Goode.
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Jason Douglas, Andrew Lincoln, Jeffrey Dean Morgan, Christian Serratos, Ross Marquand, Jordan Woods-Robinson, and Troy Jackson in The Walking Dead (2010)
"The Walking Dead": Rick Grimes and Negan.
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Hugh Dancy, Mads Mikkelsen, and Lara Jean Chorostecki in Hannibal (2013)